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VB . NET QR - Code Generator creates barcode QR - Code images in VB . NET calss, ASP.NET websites. alkylating carbocation. However, frequently the reaction is still referred to as "alkylation of alkanes by alkenes." In fact, however, alkanes are alkylated directly only under superacidic conditions (see Section 5.1.2) where no free alkenes are present and therefore the O"-donor alkanes do not compete for the carbocationic alkylating agent with the much higher nucleophilicity TC-donor alkenes. This is, as stated by Olah, the fundamental difference between conventional acid-catalyzed alkylation chemistry in which alkenes play the key role and superacidic chemistry, which proceeds on saturated alkanes in absence of alkenes. Since carbocations do not readily abstract hydride ion from secondary (or primary) carbon atoms, n-alkanes seldom enter the alkylation reaction unless they first isomerize to isoalkanes containing tertiary carbon atoms. The formation of isomeric alkylated products is explained by the ability of carbocations to undergo rearrangements. Ion 2 may participate in a series of hydride and alkyde shifts, and each carbocation thus formed may react via hydride ion transfer to form isomeric alkanes (Scheme 5.1). The formation of l-ethyl-2-methylcyclohexane in the alkylation of methylcyclopentane with propylene is also explained by the carbocationic mechanism ! Carbocation 4 formed according to the general pattern given in Eq. (5.4) undergoes rearrangement [Eq. (5.6)] with the resulting 5 cyclohexyl cation further reacting by intermolecular hydride transfer [Eq. (5.7)]. The low reactivity of cyclohexane in alkylation with alkenes is accounted for by the necessary isomerization to methylcyclopentane requiring more forcing reaction conditions: Take a look at a page that specifies a yellow background for the page and a light blue back ground (color #99F) for two of the <div> tags on the page: j(mod 41) 9 11 12 13 18 19 20 21 22 26 30 31 38 40 54 57 58 59 60 1 2 4 qr code generator vb.net codeproject QR Code Generator - MSDN - Microsoft
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