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Ideal gas: entropy change for, 159-161 fugacity of, 369-375 heat capacity of, 118-122,635 internal energy and enthalpy changes for, 67-68, 191, 198-199 property changes of mixing, 419 property relations, 191, 198-199,219 reaction equilibrium, 465 and residual property, 198-199 temperature scale, 65 Ideal-gas mixture, 120,364-368 Ideal-gas state, 64-65, 118-122, 191 Ideal solution, 384-386 chemical-reaction equilibrium, 464,466 and excess property, 386,390 properties of, 384-386 property changes of mixing for, 419-420 and Raoult's law, 327 Ideal work, 169-173,591 Immiscible systems, 553-555 Incompressible fluid, 62, 191, 194-195 Intensive property, 3,21 Intensive state, 26 Intermolecular forces, 602-608 direct electrostatic, 603-604 dispersion, 605-607 induction, 606-608 quasichemical, 616-617 Internal-combustion engine, 281-288 Internal energy, 18-19,43 differential expression for, 187-1 88, 194 of ideal gas, 67-72 microscopic view, 611-6 13 International Temperature Scale, 5 Interpolation, 662-664 Inversion curve, 249 Ionization potential (first), 606 Irreversibility, 29-30, 173-174, 239,241-244 and entropy change, 161-165, 173 Isentropic process, 159-160,212-214, 242-244,249,255-258 Isobaric process, 70, 72-73 Isothermal compressibility, 62-63, 191-192 Isothermal process, 70, 72-73 Jet engine, 289-290 Joule/Thomson coefficient, 247-248 Joule/Thomson expansion (see Throttling process) K-value for VLE, 339-346,5 13-516, 526-528,530-531 Kinetic energy, 9-10,22-23,43-44,48, 241,249 Langmuir isotherm, 569-575,579-580 Latent heat, 123-125,207-208 Riedel equation for, 125 Watson correlation for, 125 LewisrRandall rule, 385-386 and Henry's law, 404 and Raoult's law, 327 Liquefaction, 304-309 Liquidlliquid equilibrium (LLE), 541-549 Liquidlvapor equilibrium (see Vaporlliquid equilibrium) Liquids: fugacity of, 370-373 generalized density correlation, 103-104 heat capacity for, 120, 636 incompressible, 62, 191, 194-195 property changes of, 62-63, 191 P VT behavior of, 86-87,93-95 standard state for, 127 Lost work, 173-176,590-591 Mach number, 238 ~ a ~ l e 95,339,511,640-641 @, Margules equation, 408,416 Mass balance, 42-43 ~ a t h c a d @95,339,511,640-641 , Maximum velocity in flow, 239-240 Maxwell's equations, 189 MCPH, 123,199,639-640 MCPS, 161, 199,639-640 MDCPH, 132,461 Mixing process: entropy change, 367,420,424-426 Gibbs-energy change, 420,424-426 heat effect of, 366-367,420438 in ideal gas and ideal solution, 420,421 property changes, 420 Mixing rule, 378,521-522, 528-530 Molar mass, table of values for, 632-633 Molecular basis for mixture behavior, 622-626 Molecular simulation of VLE, 626-627 Molecular weight (see Molar mass) Mollier diagram, 196-197 for steam (see back endpapers) Momentum principle, 235.

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plastic, or metal like the one shown in Figure 10-27 The rod can be interchanged by simply removing the two bolts and replacing it with another rod or some other device that will deliver the movement from the wiper s arm to your prop or display The bolts used to connect the rod to the wiper arm shaft should not interfere with the mounting hardware or your electronics when the motor makes a complete revolution, so test this before setting up your display The end of the original control arm that is now connected to your steel rod will be held to the wiper s drive arm by some type of easy-to-remove C-clamp or a cotter pin, which will prevent it from falling off as the motor rotates Figure 10-28 shows the rod and all supporting hardware connected and ready to push and pull whatever may be connected to the other end of the steel rod Some extra weight besides what is offered by the heavy battery may need to be added to the platform as well, especially if your target prop is

Newton's method, 490,514,714717 Newton's second law, 3 4 9 - 1 0 , 2 3 5 Nozzle, 241-245 Open system, 20,42 Osmotic equilibrium, 580-583 Osmotic pressure, 580-583 Otto cycle, 281-283 Partial pressure, 365-366, 374 Partial property, 355-365 excess, 387 graphical interpretation, 360-363 for an ideal solution, 384-385 relations among, 357-359 Partially miscible system, 541-555 Partition function, 612-613 PengIRobinson equation, 93-95 Phase, 27,58-61 Phase change, 59-61,210 Phase diagrams: binary VLE, 317-326,330-332,529, 535 binary system, limited miscibility, 542, 537-538,550-552,554 Phase diagrams: for a pure species, 59-61 Phase equilibrium, 314-346,400-415, 507-583 criteria for, 354355, 370, 374,556 (See also Adsorption equilibrium; Liquidliquid equilibrium; Osmotic equilibrium; Solidliquid equilibrium; Solidlvapor equilibrium; Vaporlliquid equilibrium; Vaporlliquidliquid equilibrium) Phase rule, 26-28, 315-316,481-484 for adsorption equilibrium, 567 PHIB, 382,641 Polytropic process, 72-73 Potential energy: gravitational, 10-1 1,22-23,41,269 intermolecular, 602 Potential function (pair), 602-611 Lennard-Jones, 603-604 2nd virial coefficient from, 608-611 square-well, 608-609 Power-plant cycle, 269-281 Rankine, 271-275 regenerative, 275-281 analysis of, 591-596 Poynting factor: for liquid-phase fugacity, 37 1 for solid-phase fugacity, 562, 565 Pressure, 6-8 critical, 58-59 effective, for H2, 97 ), interaction (PC,, 382 table of values for, 632-633 partial, 365-366, 374 pseudocritical, 223 reduced, 90 Pressurelcomposition (Pxy) diagram, 318-319,324,328-329,528,535 Pressurelenthalpy ( P H) diagram, 211, 705-706 Pressureltemperature ( P T ) diagram, 59, 61, 320-321 Pressure/volume ( P V) diagram, 59-60, 519 Process: adiabatic, 71-72, 162-163 constant-pressure, 70,73 constant-volume, 7 1,73 isentropic, 159,212-213,242-243,245, 255-258 isothermal, 70, 72 polytropic, 72-73 thermodynamic analysis of, 590-599 throttling, 245-249 Property: critical, 58-61 table of values, 632-633 from equation of state, 202-206 excess (see Excess property) extensive and intensive, 3,21 generalized correlations, 95-105, 215-224, 380-384,646-661 of ideal-gas mixture, 120, 365-368 of ideal solution, 384386 partial (see Partial property) reduced, 90, 103,223 residual (see Residual property) of single-phase system, 186-196 of two-phase system, 207-208 (See also Thermodynamic properties) Property change of mixing, 420 and excess property, 420-422 for ideal gas and ideal solution, 420 observed behavior, 424-425.

Crystal lattice (layered network pattern)

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